Shot-noise-limited Doppler-broadened noise-immune cavity-enhanced optical heterodyne molecular spectrometry.

Shot-noise-limited Doppler-broadened (Db) noise-immune cavity-enhanced optical heterodyne molecular spectrometry (NICE-OHMS) has been realized by implementation of balanced detection. A characterization of the system based on Allan-Werle plots of the absorption coefficient, retrieved by fitting a model function to data, shows that the system has a white noise equivalent absorption per unit length per square root of bandwidth of 2.3×10-13  cm-1 Hz-1/2, solely 44% above the shot noise limit, and a detection sensitivity of 2.2×10-14  cm-1 over 200 s, both being unprecedented for Db NICE-OHMS. The white noise response follows the expected inverse square root dependence on power that is representative of a shot-noise-limited response, which confirms that the system is shot-noise-limited.